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QCE Chemistry Units 3&4 — Paper 2 Question and Response Book

QCE Chemistry Units 3&4 — Paper 2 Question and Response Book — Free Online Pack 0

Read QCE Chemistry Units 3&4 — Paper 2 Question and Response Book online for free, including every question, worked solution, marking note and diagnostic action. No public PDF download or checkout is provided.

QCE Units 3&4 External Examination 2026 Edition - Pack 0 v2.0
Updated 3 Oct 2026

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Syllabus alignment: Chemistry General senior syllabus — 2025 v1.3.

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  • Paper 1 Fri 30 Oct 2026 AM · scheduled 9:00 am Upcoming4 days left
  • Paper 2 Fri 30 Oct 2026 PM · scheduled 12:30 pm Upcoming4 days left

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QCE Chemistry Units 3&4 — Paper 2 Question and Response Book

9 questions

55 marks

Reading: 5 minutes perusal · Writing: 90 minutesFree online paper · no PDF download or checkout

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What Pack 0 covers

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Covered in this pack

  • QCAA Chemistry General senior syllabus 2025 v1.3 - Unit 3 Topic 1 - Chemical equilibrium systems - external-assessment Objectives 1-4 41 marks · 12 questions
  • QCAA Chemistry General senior syllabus 2025 v1.3 - Unit 3 Topic 2 - Oxidation and reduction - external-assessment Objectives 1-4 18 marks · 8 questions
  • QCAA Chemistry General senior syllabus 2025 v1.3 - Unit 4 Topic 1 - Properties and structure of organic materials - external-assessment Objectives 1-4 21 marks · 9 questions
  • QCAA Chemistry General senior syllabus 2025 v1.3 - Unit 4 Topic 2 - Chemical synthesis and design - external-assessment Objectives 1-4 30 marks · 9 questions

Read QCE Chemistry Units 3&4 — Paper 2 Question and Response Book online

Skill Align

Skill Align QCE Chemistry - Free Online Pack 0 Paper 2

An independently authored QCE Chemistry practice paper with worked answers and question-specific marking guidance.

Paper
Paper 2 Question and Response Book
Reading
5 minutes perusal
Writing
90 minutes
Assessment
55 marks

The official QCAA Chemistry 2025 formula and data book is supplied separately as “snr_chemistry_25_formula_data_book.pdf”. A QCAA-approved scientific or graphics calculator may be used.

Short-response questions

Questions 1-9 are short response. Answer all parts, show calculations and justify conclusions using the supplied chemical evidence.

Question 1

8 marks
Stimulus

For N₂O₄(g) ⇌ 2NO₂(g), Kc = 0.212 at a stated temperature. An equilibrium mixture contains [N₂O₄] = 0.180 mol L⁻¹ and [NO₂] = 0.195 mol L⁻¹. A separate mixture at the same temperature is prepared with [N₂O₄] = 0.250 mol L⁻¹ and [NO₂] = 0.100 mol L⁻¹.

Use the following stimulus to answer all parts of this question.
(a) 3 marks
Verify Kc for the equilibrium mixture.
(b) 3 marks
Calculate Qc for the separate mixture and predict the net direction.
(c) 2 marks
Explain the effect of decreasing the volume at constant temperature.

Question 2

3 marks
Stimulus

A buffer contains H₂PO₄⁻ and HPO₄²⁻ at 25 °C.

Use the following stimulus to answer all parts of this question.
(a) 2 marks
Explain how this buffer responds when a small amount of NaOH is added.
(b) 1 mark
State one condition under which the buffer would cease to be effective.

Question 3

5 marks
Stimulus

A cell is assembled from Fe(s)/Fe²⁺(1.0 mol L⁻¹) and Ag⁺(1.0 mol L⁻¹)/Ag(s). E°(Fe²⁺/Fe) = −0.44 V and E°(Ag⁺/Ag) = +0.80 V.

Use the following stimulus to answer all parts of this question.
Diagram Preview
Galvanic cell external wire salt bridge between half-cell solutions Fe(s) | Fe²⁺(aq) Ag⁺(aq) | Ag(s)
(a) 2 marks
Write the oxidation and reduction half-equations.
(b) 1 mark
Write the balanced overall equation.
(c) 2 marks
Calculate E°cell and explain spontaneity under standard conditions.

Question 4

5 marks
Stimulus

An unknown compound has a molecular-ion peak at m/z 102. Its IR spectrum has a strong absorption at 1740 cm⁻¹ and a band at 1200 cm⁻¹, with no broad O–H absorption. Hydrolysis produces methanol and butanoic acid.

Use the following stimulus to answer all parts of this question.
Graph Preview
100436271258718102m/zrelative abundance
(a) 1 mark
Identify the functional group supported by the IR data.
(b) 2 marks
Deduce the compound and write its condensed structural formula.
(c) 2 marks
Explain how the hydrolysis evidence distinguishes the ester from an isomeric ester.

Question 5

6 marks
Stimulus

A polyester is made from ethane-1,2-diol and hexanedioic acid. The monomers are HO–CH₂–CH₂–OH and HOOC–(CH₂)₄–COOH.

Use the following stimulus to answer all parts of this question.
Diagram Preview
Displayed monomers supplied monomer structure(s) n HO–CH₂–CH₂–OH + n HOOC–(CH₂)₄–COOH polymer product
(a) 2 marks
Draw or state the repeat unit and identify the polymerisation type.
(b) 2 marks
Account for the small-molecule product.
(c) 2 marks
Relate one structural feature to a material property.

Question 6

10 marks
Stimulus

A pilot ammonia plant compares two settings. Setting L: 380 °C, 18 MPa, single-pass equilibrium NH₃ 36%, gas processed 82 kmol h⁻¹, compressor energy 7.2 GJ t⁻¹ NH₃. Setting H: 470 °C, 28 MPa, single-pass equilibrium NH₃ 31%, gas processed 126 kmol h⁻¹, compressor energy 11.8 GJ t⁻¹ NH₃. Both use the same iron catalyst and recycle unreacted gas. The forward reaction is exothermic and reduces four gas moles to two.

Use the following stimulus to answer all parts of this question.
(a) 3 marks
Explain the effects of temperature and pressure on equilibrium and rate.
(b) 3 marks
Analyse the supplied operating evidence.
(c) 2 marks
Explain the roles of catalyst and recycle.
(d) 2 marks
Recommend a setting for an energy-constrained plant and justify the decision.

Question 7

4 marks
Stimulus

At pH 6.0, amino acid A has net charge +1 and amino acid B has net charge −1. Equal amounts are placed at the centre of an electrophoresis gel between a positive electrode and a negative electrode. An electric field is applied.

Use the following stimulus to answer all parts of this question.
(a) 2 marks
Predict the migration direction of each amino acid.
(b) 2 marks
Explain why the amino acids move in opposite directions.

Question 8

9 marks
Stimulus

A 25.00 mL reef-water sample is treated so that all acid capacity reacts 1:1 with NaOH. Standardisation gives c(NaOH) = 0.09876 mol L⁻¹. Titres are 12.42, 12.38, 12.40 and 13.06 mL. A procedural blank requires 0.20 mL NaOH.

Use the following stimulus to answer all parts of this question.
(a) 2 marks
Select the concordant titres and calculate their mean.
(b) 2 marks
Correct for the blank and calculate the amount of acid capacity in the aliquot.
(c) 2 marks
Calculate the acid capacity in mol L⁻¹.
(d) 2 marks
Explain why the blank and concordant trials matter.
(e) 1 mark
State one limitation of reporting this result as the concentration of a single acid.

Question 9

5 marks
Stimulus

Glucose ferments according to C₆H₁₂O₆(aq) → 2C₂H₅OH(aq) + 2CO₂(g). A batch begins with 18.0 kg glucose and produces 7.36 kg ethanol. Use M(glucose) = 180.0 g mol⁻¹ and M(ethanol) = 46.0 g mol⁻¹.

Use the following stimulus to answer all parts of this question.
(a) 3 marks
Calculate the theoretical ethanol mass.
(b) 1 mark
Calculate the percentage yield.
(c) 1 mark
Give one chemically plausible reason for a yield below 100%.

QCE and QCAA external assessments are administered by the Queensland Curriculum and Assessment Authority (QCAA). Skill Align is an independent publisher and is not affiliated with, authorised by, sponsored by, approved by or endorsed by QCAA or the Queensland Government.

Copyright (c) 2026 Skill Align. Free for personal, non-commercial online viewing at https://skillalign.au. You may share the Skill Align page link. Except as permitted by law or with Skill Align's prior written permission, the pack itself must not be resold, copied, redistributed, republished, automatically extracted, or uploaded to a question bank. Every question, dataset, visual, answer and marking description in this pack is original Skill Align content.

Worked Solutions And Marking Guide

General marking principles

  • Award each listed mark independently when the required chemical evidence is demonstrated.
  • Accept chemically accurate equivalent wording, balanced equations and logically equivalent calculations.
  • Apply follow-through where a prior numerical error is used consistently and the subsequent chemical method is correct.
  • Do not award conclusions that contradict the supplied data or rely on unstated evidence.

Question 1

(a) - Uses Kc = [NO₂]²/[N₂O₄]. - Substitutes the equilibrium concentrations. - Obtains Kc ≈ 0.211, consistent with 0.212.

(b) - Calculates Qc = 0.100²/0.250 = 0.0400. - Compares Qc < Kc. - Predicts net forward reaction towards NO₂.

(c) - Recognises one gas mole on the left and two on the right. - Predicts a shift towards N₂O₄, while Kc remains unchanged.

Detailed marking criteria

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Uses Kc = [NO₂]²/[N₂O₄].

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Substitutes the equilibrium concentrations.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Obtains Kc ≈ 0.211, consistent with 0.212.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Calculates Qc = 0.100²/0.250 = 0.0400.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Compares Qc < Kc.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Predicts net forward reaction towards NO₂.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Recognises one gas mole on the left and two on the right.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Predicts a shift towards N₂O₄, while Kc remains unchanged.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Question 2

(a) - States that H₂PO₄⁻ donates a proton to added OH⁻, forming HPO₄²⁻ and water. - Explains that removal of much of the added OH⁻ limits the pH increase.

(b) - States that consuming most of either conjugate component exceeds the buffer capacity.

Detailed marking criteria

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: States that H₂PO₄⁻ donates a proton to added OH⁻, forming HPO₄²⁻ and water.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Explains that removal of much of the added OH⁻ limits the pH increase.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: States that consuming most of either conjugate component exceeds the buffer capacity.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Question 3

(a) - Writes Fe(s) → Fe²⁺ + 2e⁻. - Writes Ag⁺ + e⁻ → Ag(s).

(b) - Writes Fe(s) + 2Ag⁺(aq) → Fe²⁺(aq) + 2Ag(s).

(c) - Calculates E°cell = 0.80 − (−0.44) = +1.24 V. - Uses the positive potential to identify the written reaction as spontaneous under standard conditions.

Detailed marking criteria

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Writes Fe(s) → Fe²⁺ + 2e⁻.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Writes Ag⁺ + e⁻ → Ag(s).

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Writes Fe(s) + 2Ag⁺(aq) → Fe²⁺(aq) + 2Ag(s).

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Calculates E°cell = 0.80 − (−0.44) = +1.24 V.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Uses the positive potential to identify the written reaction as spontaneous under standard conditions.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Question 4

(a) - Identifies an ester functional group from C=O and C–O absorptions without O–H.

(b) - Identifies methyl butanoate. - Writes CH₃CH₂CH₂COOCH₃.

(c) - Relates the methanol product to the –OCH₃ side. - Relates butanoic acid to the four-carbon acyl side.

Detailed marking criteria

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Identifies an ester functional group from C=O and C–O absorptions without O–H.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Identifies methyl butanoate.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Writes CH₃CH₂CH₂COOCH₃.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Relates the methanol product to the –OCH₃ side.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Relates butanoic acid to the four-carbon acyl side.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Question 5

(a) - Gives repeat unit [–O–CH₂–CH₂–O–CO–(CH₂)₄–CO–]n. - Identifies condensation polymerisation.

(b) - States that water forms when hydroxyl and carboxyl groups form ester links. - For n of each bifunctional monomer in a linear chain, accepts approximately (2n−1) water molecules or an end-group-aware equivalent.

(c) - Links polar ester groups to dipole interactions between chains. - Relates those interactions to greater cohesion or higher softening temperature than a comparable non-polar chain.

Detailed marking criteria

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Gives repeat unit [–O–CH₂–CH₂–O–CO–(CH₂)₄–CO–]n.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Identifies condensation polymerisation.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: States that water forms when hydroxyl and carboxyl groups form ester links.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: For n of each bifunctional monomer in a linear chain, accepts approximately (2n−1) water molecules or an end-group-aware equivalent.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Links polar ester groups to dipole interactions between chains.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Relates those interactions to greater cohesion or higher softening temperature than a comparable non-polar chain.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Question 6

(a) - Explains that lower temperature favours exothermic ammonia formation. - Explains that higher temperature increases reaction rate. - Explains that higher pressure favours the side with fewer gas moles.

(b) - Compares 36% with 31% single-pass equilibrium NH₃. - Compares the higher 126 kmol h⁻¹ throughput with 82 kmol h⁻¹. - Compares compressor energy of 11.8 with 7.2 GJ t⁻¹ NH₃.

(c) - States that the catalyst increases rate without changing equilibrium composition. - States that recycle improves overall reactant utilisation after product removal.

(d) - Recommends Setting L for the stated energy constraint. - Justifies the recommendation using its lower compression energy together with its higher single-pass equilibrium percentage, while acknowledging lower throughput.

Detailed marking criteria

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Explains that lower temperature favours exothermic ammonia formation.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Explains that higher temperature increases reaction rate.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Explains that higher pressure favours the side with fewer gas moles.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Compares 36% with 31% single-pass equilibrium NH₃.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Compares the higher 126 kmol h⁻¹ throughput with 82 kmol h⁻¹.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Compares compressor energy of 11.8 with 7.2 GJ t⁻¹ NH₃.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: States that the catalyst increases rate without changing equilibrium composition.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: States that recycle improves overall reactant utilisation after product removal.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part d (1 mark)

Awards one mark for accurately establishing this question-specific point: Recommends Setting L for the stated energy constraint.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part d (1 mark)

Awards one mark for accurately establishing this question-specific point: Justifies the recommendation using its lower compression energy together with its higher single-pass equilibrium percentage, while acknowledging lower throughput.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Question 7

(a) - Predicts A migrates towards the negative electrode. - Predicts B migrates towards the positive electrode.

(b) - Relates direction to attraction between opposite charges. - Recognises that the stated pH produces different net ionic forms.

Detailed marking criteria

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Predicts A migrates towards the negative electrode.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Predicts B migrates towards the positive electrode.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Relates direction to attraction between opposite charges.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Recognises that the stated pH produces different net ionic forms.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Question 8

(a) - Rejects 13.06 mL as discordant. - Calculates mean concordant titre = 12.40 mL.

(b) - Subtracts the 0.20 mL blank to obtain 12.20 mL. - Calculates n = 0.09876 × 0.01220 = 1.205 × 10⁻³ mol.

(c) - Divides by 0.02500 L. - Obtains 0.04820 mol L⁻¹.

(d) - Explains that the blank corrects titrant consumed by reagents/apparatus rather than sample acid. - Explains that concordance supports precision and identifies an anomalous titre.

(e) - Explains that the titration measures combined acid-neutralising capacity and does not identify individual acid species.

Detailed marking criteria

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Rejects 13.06 mL as discordant.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Calculates mean concordant titre = 12.40 mL.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Subtracts the 0.20 mL blank to obtain 12.20 mL.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Calculates n = 0.09876 × 0.01220 = 1.205 × 10⁻³ mol.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Divides by 0.02500 L.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Obtains 0.04820 mol L⁻¹.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part d (1 mark)

Awards one mark for accurately establishing this question-specific point: Explains that the blank corrects titrant consumed by reagents/apparatus rather than sample acid.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part d (1 mark)

Awards one mark for accurately establishing this question-specific point: Explains that concordance supports precision and identifies an anomalous titre.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part e (1 mark)

Awards one mark for accurately establishing this question-specific point: Explains that the titration measures combined acid-neutralising capacity and does not identify individual acid species.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Question 9

(a) - Calculates 100 mol glucose. - Uses the 1:2 ratio to obtain 200 mol ethanol. - Obtains 9.20 kg theoretical ethanol.

(b) - Calculates 7.36/9.20 × 100 = 80.0%.

(c) - Identifies incomplete fermentation, competing microbial reactions or ethanol loss during separation as a plausible cause.

Detailed marking criteria

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Calculates 100 mol glucose.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Uses the 1:2 ratio to obtain 200 mol ethanol.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part a (1 mark)

Awards one mark for accurately establishing this question-specific point: Obtains 9.20 kg theoretical ethanol.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part b (1 mark)

Awards one mark for accurately establishing this question-specific point: Calculates 7.36/9.20 × 100 = 80.0%.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Part c (1 mark)

Awards one mark for accurately establishing this question-specific point: Identifies incomplete fermentation, competing microbial reactions or ethanol loss during separation as a plausible cause.

Acceptable alternatives: Accept chemically equivalent wording or a logically equivalent calculation.

Do not credit by itself: Do not award an unsupported conclusion or a response that contradicts the supplied stimulus.

Diagnostic Checklist

TopicQuestionsMarksMarks LostAction
Unit 3 Topic 1 - Chemical equilibrium systems Q1, Q2, Q8 20 ___ Review equilibrium, Kc, Q, Ksp, acids, bases, buffers, indicators and volumetric analysis.
Unit 3 Topic 2 - Oxidation and reduction Q3 5 ___ Review oxidation states, half-equations, galvanic and electrolytic cells, cell potentials and electrolysis calculations.
Unit 4 Topic 1 - Properties and structure of organic materials Q4, Q7 9 ___ Review organic structure, nomenclature, isomerism, reactions, properties, spectra, chromatography and electrophoresis.
Unit 4 Topic 2 - Chemical synthesis and design Q5, Q6, Q9 21 ___ Review Haber and contact processes, ethanol production, fuel cells, yields, polymers, peptides and carbohydrates.

What is included

Paper 1 Combined Independent Practice Book questions (55 marks)

Paper 2 Question and Response Book questions (55 marks)

Links to the current official examination resources supplied separately by the assessment authority

Worked solutions and marking guidance shown online

Diagnostic checklist shown online

Free browser viewing with no checkout

No PDF or downloadable file

How to use this pack

  1. Attempt: Open the complete paper online and work under the timing and conditions shown on this page.
  2. Mark: Use the supplied worked solutions or response support and marking guidance to check answers and method.
  3. Review: Use the supplied diagnostic or review support to identify the next areas for revision.

Is this pack right for you?

Designed for

Students, parents, teachers and tutors who want to inspect a complete online QCE Chemistry Units 3&4 example before choosing a released PDF pack.

Product at a glance

  • QCE Chemistry Units 3&4
  • 2026 edition · Pack 0 · v2.0
  • 2 online papers
  • Free online view · no checkout or PDF download
  • Free to view online
  • No monthly Online Practice subscription required

Compare before buying

Pack 0 is the free online showcase for this course. Other pack numbers identify separate original products; they do not indicate difficulty or a required order.

Official examination resources

Open these current official resources alongside the Skill Align paper. They remain hosted and controlled by the assessment authority and are not republished by Skill Align.

Official QCAA Chemistry General senior syllabus 2025 v1.3 Current syllabus for students completing Chemistry in 2026 or beyond.
Official QCAA Chemistry 2025 formula and data book Use this separate official companion resource during each timed attempt; no custom Skill Align reference pages are embedded.

Questions about this exam pack

What is included in Chemistry Free Online - Pack 0?

Pack 0 includes 2 full-length showcase papers, worked solutions, marking guidance and diagnostic checklists, all shown online.

Is Pack 0 really free?

Yes. Pack 0 can be read online without checkout or a monthly subscription.

What does Pack 0 mean?

Pack 0 identifies the free online showcase for this course. Other pack numbers identify separate original products; they do not indicate difficulty or a required completion order.

Can I download Pack 0 as a PDF?

No. Pack 0 is intentionally online-only and no downloadable PDF is provided.

Are these official assessment authority examination questions?

No. The questions are original Skill Align material. Skill Align is independent and is not affiliated with, authorised by, sponsored by, approved by, or endorsed by any state assessment authority.

Independent practice resource

Queensland Certificate of Education (QCE) subjects and external assessments are administered by the Queensland Curriculum and Assessment Authority (QCAA). Skill Align is an independent publisher and is not affiliated with, authorised by, sponsored by, approved by, or endorsed by QCAA or the Queensland Government.

Each exam pack is listed with a pack label so buyers can distinguish separate original products in the same course series. Pack numbers do not indicate difficulty or a required completion order.

2026 exam timetable reference View QCAA 2026 timetable
  • Paper 1 Fri 30 Oct 2026 AM · scheduled 9:00 am Upcoming4 days left
  • Paper 2 Fri 30 Oct 2026 PM · scheduled 12:30 pm Upcoming4 days left

QCAA schedules morning and afternoon sessions at 9:00 am and 12:30 pm. Your school may start within the permitted 15-minute window; check its final directions and any clash allocation.